Porous iron pellets for AMS C-14 analysis of small samples down to ultra-microscale size (10-25 mu gC)

We developed the use of a porous iron pellet as a catalyst for AMS C-14 analysis of small samples down to ultra-microscale size (10-25 mu gC). It resulted in increased and more stable beam currents through our HVEE 4130 C-14 AMS system, which depend smoothly on the sample size. We find that both the expected decrease of oxalic acid standards and increase of backgrounds with decreasing sample size, due to increasing influence of contamination, are reproducible. Using a mass-dependent background correction for dead (1.0 +/- 0.4 mu gC) and modern (0.25 +/- 0.10 mu gC) contamination, we obtain reliable results for small samples down to 10 mu gC and possibly smaller. Due to our low graphitization yield for ultra-small samples (increases from 40% to 80% on average with sample size), we measured graphite standards as small as 3 mu gC. The standard deviation of the corrected activity is about 5% for a 10-mu gC HOxII standard.

Here we report the iron pellet technique, which is new to the best of our knowledge. It is generally applicable for AMS C-14 laboratories that want to measure small samples down to ultra-microscale size. As an illustrative test-case, we analyze C-14 data for IAEA-05, C7 and C8 samples with masses ranging from 15 to 300 mu gC. (C) 2009 Elsevier B.V. All rights reserved.