High-Performance Solution-Processable Poly(p-phenylene vinylene)s for Air-Stable Organic Field-Effect Transistors

Albert J.J.M. van Breemen; Peter T. Herwig; Ceciel H.T. Chlon; Jörgen Sweelssen; Herman F.M. Schoo; Estrella Mena Benito; Dago M. de Leeuw; Christina Tanase; Jurjen Wildeman; Paul W.M. Blom

doi:10.1002/adfm.200400445

High-Performance Solution-Processable Poly(p-phenylene vinylene)s for Air-Stable Organic Field-Effect Transistors

Albert J.J.M. van Breemen, Peter T. Herwig, Ceciel H.T. Chlon, Jörgen Sweelssen, Herman F.M. Schoo, Estrella Mena Benito, Dago M. de Leeuw, Christina Tanase, Jurjen Wildeman, Paul W.M. Blom

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Abstract

The influence of the substitution pattern (unsymmetrical or symmetrical), the nature of the side chain (linear or branched), and the processing of several solution processable alkoxy-substituted poly(p-phenylene vinylene)s (PPVs) on the charge-carrier mobility in organic field-effect transistors (OFETs) is investigated. We have found the highest mobilities in a class of symmetrically substituted PPVs with linear alkyl chains (e.g., R1, R2 = n-C11H23, R3 = n-C18H37). We have shown that the mobility of these PPVs can be improved significantly up to values of 10-2 cm2 V-1 s-1 by annealing at 110°C. In addition, these devices display an excellent stability in air and dark conditions. No change in the electrical performance is observed, even after storage for thirty days in humid air.

Original language	English
Pages (from-to)	872 - 876
Number of pages	5
Journal	Advanced Functional Materials
Volume	15
Issue number	5
DOIs	https://doi.org/10.1002/adfm.200400445
Publication status	Published - 2005

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Breemen, A. J. J. M. V., Herwig, P. T., Chlon, C. H. T., Sweelssen, J., Schoo, H. F. M., Benito, E. M., Leeuw, D. M. D., Tanase, C., Wildeman, J., & Blom, P. W. M. (2005). High-Performance Solution-Processable Poly(p-phenylene vinylene)s for Air-Stable Organic Field-Effect Transistors. Advanced Functional Materials, 15(5), 872 - 876. https://doi.org/10.1002/adfm.200400445

@article{bf13c1f147a64852999337448cfad6e1,

title = "High-Performance Solution-Processable Poly(p-phenylene vinylene)s for Air-Stable Organic Field-Effect Transistors",

abstract = "The influence of the substitution pattern (unsymmetrical or symmetrical), the nature of the side chain (linear or branched), and the processing of several solution processable alkoxy-substituted poly(p-phenylene vinylene)s (PPVs) on the charge-carrier mobility in organic field-effect transistors (OFETs) is investigated. We have found the highest mobilities in a class of symmetrically substituted PPVs with linear alkyl chains (e.g., R1, R2 = n-C11H23, R3 = n-C18H37). We have shown that the mobility of these PPVs can be improved significantly up to values of 10-2 cm2 V-1 s-1 by annealing at 110°C. In addition, these devices display an excellent stability in air and dark conditions. No change in the electrical performance is observed, even after storage for thirty days in humid air.",

author = "Breemen, {Albert J.J.M. van} and Herwig, {Peter T.} and Chlon, {Ceciel H.T.} and J{\"o}rgen Sweelssen and Schoo, {Herman F.M.} and Benito, {Estrella Mena} and Leeuw, {Dago M. de} and Christina Tanase and Jurjen Wildeman and Blom, {Paul W.M.}",

note = "Relation: http://www.rug.nl/natuurkunde/ date_submitted:2005 Rights: University of Groningen. Materials Science Centre",

year = "2005",

doi = "10.1002/adfm.200400445",

language = "English",

volume = "15",

pages = "872 -- 876",

journal = "Advanced Functional Materials",

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number = "5",

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TY - JOUR

T1 - High-Performance Solution-Processable Poly(p-phenylene vinylene)s for Air-Stable Organic Field-Effect Transistors

AU - Breemen, Albert J.J.M. van

AU - Herwig, Peter T.

AU - Chlon, Ceciel H.T.

AU - Sweelssen, Jörgen

AU - Schoo, Herman F.M.

AU - Benito, Estrella Mena

AU - Leeuw, Dago M. de

AU - Tanase, Christina

AU - Wildeman, Jurjen

AU - Blom, Paul W.M.

N1 - Relation: http://www.rug.nl/natuurkunde/ date_submitted:2005 Rights: University of Groningen. Materials Science Centre

PY - 2005

Y1 - 2005

N2 - The influence of the substitution pattern (unsymmetrical or symmetrical), the nature of the side chain (linear or branched), and the processing of several solution processable alkoxy-substituted poly(p-phenylene vinylene)s (PPVs) on the charge-carrier mobility in organic field-effect transistors (OFETs) is investigated. We have found the highest mobilities in a class of symmetrically substituted PPVs with linear alkyl chains (e.g., R1, R2 = n-C11H23, R3 = n-C18H37). We have shown that the mobility of these PPVs can be improved significantly up to values of 10-2 cm2 V-1 s-1 by annealing at 110°C. In addition, these devices display an excellent stability in air and dark conditions. No change in the electrical performance is observed, even after storage for thirty days in humid air.

AB - The influence of the substitution pattern (unsymmetrical or symmetrical), the nature of the side chain (linear or branched), and the processing of several solution processable alkoxy-substituted poly(p-phenylene vinylene)s (PPVs) on the charge-carrier mobility in organic field-effect transistors (OFETs) is investigated. We have found the highest mobilities in a class of symmetrically substituted PPVs with linear alkyl chains (e.g., R1, R2 = n-C11H23, R3 = n-C18H37). We have shown that the mobility of these PPVs can be improved significantly up to values of 10-2 cm2 V-1 s-1 by annealing at 110°C. In addition, these devices display an excellent stability in air and dark conditions. No change in the electrical performance is observed, even after storage for thirty days in humid air.

U2 - 10.1002/adfm.200400445

DO - 10.1002/adfm.200400445

M3 - Article

VL - 15

SP - 872

EP - 876

JO - Advanced Functional Materials

JF - Advanced Functional Materials

IS - 5

ER -

High-Performance Solution-Processable Poly(p-phenylene vinylene)s for Air-Stable Organic Field-Effect Transistors

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